STEREOSPECIFIC ALPHA-ALKOXYSTANNANE COUPLINGS WITH ACYL CHLORIDES - TOTAL SYNTHESIS OF (+)-GONIOFUFURONE

被引：62

作者：

YE, JH

BHATT, RK

FALCK, JR

机构：

[1] UNIV TEXAS,SOUTHWESTERN MED CTR,DEPT MOLEC GENET,DALLAS,TX 75235

[2] UNIV TEXAS,SOUTHWESTERN MED CTR,DEPT PHARMACOL,DALLAS,TX 75235

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 50期

关键词：

C-GLYCOSIDE; PALLADIUM; STILLE COUPLING; ANTICANCER; TIN;

D O I：

10.1016/S0040-4039(00)61436-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stereospecific C-glycoside formation via Pd/Cu mediated coupling of PhCOCI with cyclic alpha-alkoxystannane 6, derived from D-glucurono-6,3-lactone, was the key transformation in a concise total synthesis of the anticancer agent (+)-goniofufurone.

引用

页码：8007 / 8010

页数：4

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