PHOTOSUBSTITUTION OF 1,2,4,5-TETRACYANOBENZENE BY ETHERS

被引：16

作者：

OHASHI, M

TSUJIMOTO, K

FURUKAWA, Y

机构：

[1] Department of Materials Science, University of Electro-communications, Chofu

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 05期

关键词：

D O I：

10.1039/p19790001147

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Irradiation of a mixture of 1,2,4,5-tetracyanobenzene and diethyl ether, tetrahydrofuran, or tetrahydropyran gave the corresponding substitution product, 1-ethoxy-1-(2,4,5-tricyanophenyl)ethane, tetrahydro-2-(2,4,5-tricyanophenyl) furan, or tetrahydro-2-(2,4,5-tricyanophenyl)pyran. Three possible mechanisms involving electron transfer are discussed.

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页码：1147 / 1149

页数：3

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