ORGANOPHOSPHORUS COMPOUNDS .39. METHODS FOR PREPARATION OF CHLOROETHYLPHOSPHONIC ACID DICHLORIDES, CLCH2CH2P(O)CL2 AND CH3CHCLP(O)CL2

被引:16
作者
MAIER, L
机构
[1] Monsanto Research S.A, Zürich, 8050, Eggbühlstrasse
关键词
D O I
10.1002/hlca.19690520516
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It is shown that the KINNEAR‐PERREN reaction with ClCH2CH2Cl, PCl3, and AlCl3 produces the two possible isomers ClCH2CH2P(O)Cl2 and CH3CHClP(O)Cl2. Methods for the preparation of pure ClCH2CH2P(O)Cl2 and pure CH3CHClP(O)Cl2 are described. The physical properties of a number of chloroethyl groups containing phosphorus compounds are listed. Copyright © 1969 Verlag GmbH & Co. KGaA, Weinheim
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页码:1337 / &
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