MANGANESE(II)ALKOXIDES

被引：32

作者：

HORVATH, B ^{[1
]}

MOSELER, R ^{[1
]}

HORVATH, EG ^{[1
]}

机构：

[1] UNIV LONDON QUEEN MARY COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1979年 / 449卷 / FEB期

关键词：

D O I：

10.1002/zaac.19794490103

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of novel, air sensitive alkoxides of Mn(II) were prepared by alcoholysis reaction of Mn{N(SiMe3)2}2 · (THF), including sterically highly hindered derivatives soluble in organic solvents. The products, characterized by elemental analysis, reflectance spectroscopy and chemical behavior, range from amorphous coordination polymers and gelatinous fibers to (probably monomeric) crystals. Earlier literature descriptions of several Mn(II) alkoxides is corrected. Some oxidation results are discussed. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：41 / 51

页数：11

共 33 条

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