GAMMA-TRIBUTYLSTANNYL-BETA-METALATED ACROLEIN - A VERSATILE SYNTHON

被引：34

作者：

MAREK, I

ALEXAKIS, A

NORMANT, JF

机构：

[1] Laboratoire de Chimie des Organo-éléments, associé au C.N.R.S., 75230 Paris Cedex 05, Tour 44-45

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 44期

关键词：

STANNOCUPRATION; D2; D3 ACROLEIN EQUIVALENT; DIETHOXYPROPYNE; VINYL TIN;

D O I：

10.1016/0040-4039(91)80163-Z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stannocupration of the diethoxypropyne affords very selectively the title compound which can be alkylated with various electrophiles.

引用

收藏

页码：6337 / 6340

页数：4

相关论文

共 40 条

[1] ALKENYL COPPER REAGENTS .18. CARBOCUPRATION OF ACETYLENIC ACETALS AND KETALS SYNTHESIS OF MANICONE, GERANIAL AND 2,4 (E,Z)-DIENALS
ALEXAKIS, A
COMMERCON, A
COULENTIANOS, C
NORMANT, JF
[J]. TETRAHEDRON, 1984, 40 (04) : 715 - 731
[2] ORGANOVINYLCOPPER COMPOUNDS .5. REGIOSELECTIVITY IN ADDITION OF ALKYL COPPER-MAGNESIUM BROMIDE REAGENTS ON VARIOUS PROPARGYL DERIVATIVES
ALEXAKIS, A
NORMANT, JF
VILLIERAS, J
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1975, 1 (01): : 43 - 58
[3] VINYL ORGANOCOPPER COMPOUNDS .4. STUDY ON REGIOSELECTIVITY OF ADDITION OF ALKYLCOPPER COMPOUND TO BETA AND GAMMA FUNCTIONAL ALKYNES
ALEXAKIS, A
NORMANT, J
VILLIERAS, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 96 (03) : 471 - 485
[4] BAEKELMANS P, 1968, B SOC CHIM BELG, V77, P185
[5] THE MECHANISM OF THE LITHIUM HALOGEN INTERCHANGE REACTION - A REVIEW OF THE LITERATURE
BAILEY, WF
PATRICIA, JJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 352 (1-2) : 1 - 46
[6] REACTION OF ORGANOTIN HYDRIDES WITH ACETYLENIC ALCOHOLS
ENSLEY, HE
BUESCHER, RR
LEE, K
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (03) : 404 - 408
[7] FLEMING I, 1981, J CHEM SOC P1, V1, P2527
[8] GORGUES A, 1980, ORG SYYNTH, V59, P10
[9] HOYASHI K, 1967, J ORGANOMET CHEM, V10, P81
[10] SPECTROSCOPIC AND CHEMICAL EVIDENCE FOR THE REVERSIBLE FORMATION OF VINYLCOPPER INTERMEDIATES IN THE STANNYLCUPRATION OF TERMINAL ALKYNES
HUTZINGER, MW
SINGER, RD
OEHLSCHLAGER, AC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (25) : 9397 - 9398

← 1 2 3 4 →