BIS(PYRAZOL-1-YL)PROPANE AS A BULKY LIGAND - X-RAY CRYSTAL-STRUCTURE DETERMINATION OF ITS ADDUCT WITH ZINC(II) CHLORIDE

被引：15

作者：

BOVIO, B ^{[1
]}

CINGOLANI, A ^{[1
]}

BONATI, F ^{[1
]}

机构：

[1] UNIV CAMERINO,DIPARTIMENTO SCI CHIM,I-62032 CAMERINO,ITALY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 610卷 / 04期

关键词：

BIS(PYRAZOL-1-YL)PROPANE ZINC(II) COMPLEX; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19926100125

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The steric misfit between a geminal bis(pyrazol-1-yl)propane ligand and tetrahedral coordination leads to distortion of the latter in the title compound: N-Zn-N is 89.5(1)-degrees, Cl-Zn-Cl 116.78(5)-degrees. Comparison of the Zn-N (2.058(3), 2.046(3) angstrom) and Zn-Cl (2.209(1), 2.229(1) angstrom) distances with those of related compounds evidences the steric bulkiness of the title ligand.

引用

页码：151 / 156

页数：6

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