SYNTHESIS OF OPTICALLY-ACTIVE PHOSPHORUS-COMPOUNDS VIA METAL PHOSPHINITES GENERATED BY REACTION OF OPTICALLY-ACTIVE SELENOPHOSPHINATES WITH PHENYLLITHIUM

被引：14

作者：

KAWASHIMA, T

IWANAGA, H

OKAZAKI, R

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 09期

关键词：

D O I：

10.1246/cl.1993.1531

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sequential treatment of optically active Se-benzyl t-butylphenylselenophosphinate with PhLi and then with electrophiles such as alkyl halides and elemental selenium gave optically active phosphorus compounds in good chemical and optical yields with a retention of configuration at phosphorus atom, together with benzyl phenyl selenide.

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页码：1531 / 1532

页数：2

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