STEREOSPECIFICITY OF DICHLOROBIS(ETHYLENEDIAMINE)COBALT(III) ION IN AN OPTICALLY ACTIVE SOLVENT

被引：3

作者：

SMITH, AA

HAINES, RA

机构：

[1] Department of Chemistry, University of Western Ontario, London, Ontario

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 23期

关键词：

D O I：

10.1021/ja01051a015

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A stereospecific substitution reaction for the two chloride ligands in cis-dichlorobis(ethylenediamine)-cobalt(III) chloride by an optically active solvent, 1,2-propanediol, has been observed. The study follows the reactions of the optical and geometrifcal isomers of the complex when they are dissolved in a particular optical isomer of the solvent. Absorption spectra and circular dichroism data have been interpreted as showing the solvent coordinated as a bidentate ligand with stereospecificity imposed upon the system by conformational interactions. © 1969, American Chemical Society. All rights reserved.

引用

页码：6280 / &

共 18 条

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