VIBRATIONAL-SPECTRA AND NORMAL COORDINATE ANALYSIS OF 3,3,3-TRIFLUOROPROPENE AND HEXAFLUOROPROPENE

被引：15

作者：

CHRISTEN, D ^{[1
]}

HOFFMANN, V ^{[1
]}

KLAEBOE, P ^{[1
]}

机构：

[1] UNIV TUBINGEN,INST PHYS & THEORET CHEM,D-7400 TUBINGEN 1,FED REP GER

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES | 1979年 / 34卷 / 11期

关键词：

D O I：

10.1515/zna-1979-1111

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The infrared spectra of 3,3,3-trifluoropropene and hexafluoropropene were studied in the vapour phase and in solution between 4000 and 40 cm−1. Raman spectra of the compounds as vapours and liquids were recorded and polarization data obtained. The spectra of both molecules are interpreted in terms of Cs symmetry. Complete vibrational assignments, including the torsional mode, are presented, based upon infrared and Raman vapour contours, Raman polarization measurements and the results of a normal coordinate analysis. © 1979, Walter de Gruyter. All rights reserved.

引用

页码：1320 / 1329

页数：10

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