SYNTHETIC METHODS AND REACTIONS .74. HEXAMETHYLDISILANE-IODINE - CONVENIENT INSITU GENERATION OF IODOTRIMETHYLSILANE

被引：77

作者：

OLAH, GA

NARANG, SC

GUPTA, BGB

MALHOTRA, R

机构：

[1] Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, Los Angeles, California, 90 007, University Park

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 08期

关键词：

D O I：

10.1002/anie.197906121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organic syntheses involving iodotrimethylsilane, e.g. cleavage of esters, ethers, snd carbamates under mild conditions, have advantages but Me3SiI is not readily obtainable and is also a sensitive compound. These difficulties are overcome by the Me3SiSiMe3/I2 reagent which can be used for convenient in‐situ generation of Me3SiI. (Formula Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：612 / 614

页数：3

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