UNUSUAL STEREOSELECTIVITY IN THE REDUCTION OF BICYCLO[3.3.0]OCT-2-EN-8-ONE BY THERMOANAEROBIUM-BROCKII ALCOHOL-DEHYDROGENASE

被引：11

作者：

KELLY, DR

LEWIS, JD

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 19期

关键词：

D O I：

10.1039/c39910001330

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Thermoanaerobium brockii alcohol dehydrogenase (TBADH) catalysed reduction of the racemic bicyclic ketone 5 gives epimeric alcohols derived from the same enantiomeric series, the reduction is enantioselective but not diasteroselective, an unusual result for a single enzyme.

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页码：1330 / 1332

页数：3

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