A NEW 1-DIMENSIONAL MOLYBDENUM PHOSPHATE - SYNTHESIS AND STRUCTURE OF [(CH3)(4)N][MN(2)MO(6)O(12)(OH)(4)(PO4)(HPO4)(H2PO4)(2)]CENTER-DOT-4H(2)O

被引:19
作者
LIGHTFOOT, P
MASSON, D
机构
[1] School of Chemistry, University of St Andrews, St Andrews
关键词
MOLYBDENUM; MANGANESE; PHOSPHATE;
D O I
10.1016/0025-5408(95)00067-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)(4)N][Mn2Mo6O12(OH)(4)(PO4)(HPO4)(H2PO4)(2)].4H(2)O has been prepared hydrothermally. It crystallises in the triclinic system, P-1, with a = 12.583(4), b = 14.322(4), c = 12.365(5)Angstrom, alpha = 104.70(3)degrees, beta = 117.02(3)degrees and gamma = 85.14(3)degrees. The structure is based on the [Mo6O12(OH)(3)(HxPO4)(4)](n-) anion previously observed in several other molybdenophosphates. These units are linked together by two different manganese-containing layers into infinite anionic chains, which are linked together only by intervening TMA cations and H-bonds.
引用
收藏
页码:1005 / 1013
页数:9
相关论文
共 9 条
[1]  
Beurskens P. T., 1992, DIRDIF PROGRAM SYSTE
[2]   BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].
BROWN, ID ;
ALTERMATT, D .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247
[3]  
Costentin G., 1993, REV INORG CHEM, V13, P77
[4]   [ET4N]6[NA14MO24P17O97(OH)31].XH2O - A HOLLOW CLUSTER FILLED WITH 12-NA+ IONS AND A H3PO4 MOLECULE [J].
HAUSHALTER, RC ;
LAI, FW .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (06) :743-746
[5]   SYNTHESIS OF A NEW ONE-DIMENSIONAL SODIUM MOLYBDENUM PHOSPHATE POLYMER - STRUCTURE OF [(H3O)2NAMO6P4O24(OH)7]2- [J].
HAUSHALTER, RC ;
LAI, FW .
INORGANIC CHEMISTRY, 1989, 28 (15) :2904-2905
[6]   REDUCED MOLYBDENUM PHOSPHATES - OCTAHEDRAL TETRAHEDRAL FRAMEWORK SOLIDS WITH TUNNELS, CAGES, AND MICROPORES [J].
HAUSHALTER, RC ;
MUNDI, LA .
CHEMISTRY OF MATERIALS, 1992, 4 (01) :31-48
[7]   HYDROTHERMAL SYNTHESIS, STRUCTURE, AND SORPTION PROPERTIES OF THE NEW MICROPOROUS FERRIC MOLYBDENUM PHOSPHATES [(CH3)4N]2(NH4)2[FE2MO12O30(H2PO4)6(HPO4)2].NH2O AND [(CH3)4N]2NA4[FE3MO12O30(HXPO4)8].NH2O [J].
MEYER, LA ;
HAUSHALTER, RC .
INORGANIC CHEMISTRY, 1993, 32 (09) :1579-1586
[8]   HYDROTHERMAL SYNTHESIS OF A LAYERED ZINC MOLYBDENUM PHOSPHATE WITH OCTAHEDRAL AND TETRAHEDRAL ZINC - STRUCTURE OF (TMA)2(H3O)2[ZN3MO12O30(HPO4)2(H2PO4)6].11.5H2O [J].
MUNDI, LA ;
HAUSHALTER, RC .
INORGANIC CHEMISTRY, 1992, 31 (14) :3050-3053
[9]  
1985, TEXSAN CRYSTAL STRUC