PEROXIDE-INITIATED ADDITION OF SOME POLYFLUOROCHLORO- AND POLYFLUOROBROMOALKANES TO SOME HYDROCARBON OLEFINS

被引：17

作者：

TARRANT, P

TANDON, JP

机构：

[1] Department of Chemistry, University of Florida, Gainesville

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 04期

关键词：

D O I：

10.1021/jo01256a019

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Both CF3CF2CCl3 and CF2ClCF2CCl3 have been found to give reasonable yields of simple addition products with olefins in the presence of benzoyl peroxide. The products of dehydrohalogenations of the adducts are described. The preferred reaction of CCl3CF2CF2Br is by cleavage of the C-Br bond rather than the C-Cl bond. Other telogens such as CF2BrCF2Br, CF3CFBrCF2Br and CFClBrClCFClBr react with ethylene to give 1:1 adducts. Certain polyhaloalkanes such as CF3CFBrCFBrCF3 and particularly CF3CClBrCFBrCF3 lose bromine readily in the presence of peroxide. © 1969, American Chemical Society. All rights reserved.

引用

页码：864 / &

共 12 条

[1]

BURTON DJ, 1966, TETRAHEDRON LETT, P5163

[2] THERMAL SYNTHESES OF TELOMERS OF FLUORINATED OLEFINS .3. PERFLUOROPROPENE TELOMER BROMIDES [J].