ELECTRONIC SPECTRA OF BINUCLEAR MOLYBDENUM(2) CARBOXYLATES

被引：53

作者：

DUBICKI, L

MARTIN, RL

机构：

[1] Department of Inorganic Chemistry, University of Melbourne, Parkville, VIC

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 08期

关键词：

D O I：

10.1071/CH9691571

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electronic spectra of binuclear molybdenum(II) acetate, benzoate, p-fluorobenzoate, and pentafluorobutyrate show intense absorption at ≃ 30000cm-1 which may, in part, be due to strong Mo-Mo bonding. The binuclear structure is characterized by a weak band at ≃ 23000 cm-1 which displays extensive vibrational fine structure. A semi-empirical molecular orbital calculation is used as an aid in the interpretation of the spectra. © 1969, CSIRO. All rights reserved.

引用

页码：1571 / &

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