Excess free energy of a two-component mixture of hard spheres slightly different in size

被引:12
作者
Bellemans, A. [1 ]
Orban, J. [1 ]
机构
[1] Univ Texas Austin, Ctr Stat Mech & Thermodynam, Austin, TX 78712 USA
关键词
D O I
10.1016/0009-2614(68)85016-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The excess free energy g(E) of a misture of hard spheres with slightly different radii is evaluated numerically. Within the fluid region g(E)/kT is always very small: in the solid region g(E)/kT becomes definitely positive.
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页码:253 / 254
页数:2
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