FUSION OF MERCURY - A NEW CERTIFIED STANDARD FOR DIFFERENTIAL SCANNING CALORIMETRY

被引：9

作者：

CALLANAN, JE ^{[1
]}

MCDERMOTT, KM ^{[1
]}

WESTRUM, EF ^{[1
]}

机构：

[1] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1990年 / 22卷 / 03期

关键词：

D O I：

10.1016/0021-9614(90)90192-S

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

From the results of adiabatic-calorimetric measurements, mercury has been certified as a standard reference material for temperature and enthalpy of fusion for differential scanning calorimetry. The fusion temperature is (234.30 ± 0.03) K and the molar enthalpy of fusion is (2.301 ± 0.001) kJ·mol-1. Adiabatic-calorimetric measurements made by heating continuously at 0.00017 K·s-1 through the transition showed a fusion temperature of (234.32 ± 0.03) K. Differential-scanning-calorimetric measurements gave a fusion temperature of (234.34 ± 048) K. © 1990.

引用

页码：225 / 230

页数：6

共 26 条

[1] THERMODYNAMIC PROPERTIES OF SOLID MERCURY FROM 150-K TO 234-K [J].