METALATION OF POLYMETHYLNAPHTHALENES

被引：11

作者：

DUNKELBLUM, E ^{[1
]}

HART, H ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 20期

关键词：

D O I：

10.1021/jo01334a007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of several polymethylnaphthalenes with excess n-BuLi-TMEDA in THF-hexane resulted mainly in monometalation of a methyl substituent. In contrast with what might be expected from simple molecular orbital calculations, metalation of a C2 methyl group was preferred over that of a C4 methyl group. © 1979, American Chemical Society. All rights reserved.

引用

页码：3482 / 3485

页数：4

共 13 条

[1]

Adamov M. N., 1967, Theoretical and Experimental Chemistry, V3, P249, DOI 10.1007/BF01112375

[2] CATALYTIC TELOMERIZATION REACTION OF ETHYLENE WITH AROMATIC HYDROCARBONS [J].