MECHANISTIC MODELING OF THE PYROLYSIS OF NORMAL-HEXANE

被引：8

作者：

BILLAUD, F

ELYAHYAOUI, K

BARONNET, F

机构：

[1] Département de Chimie Physique des Réactions, URA n0328 CNRS, INPL - ENSIC, 54001 Nancy

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 1991年 / 19卷

关键词：

FREE RADICAL CHAIN MECHANISM; NORMAL-HEXANE; MECHANISTIC MODEL; PYROLYSIS;

D O I：

10.1016/0165-2370(91)80033-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A mechanistic model of the thermal decomposition reactions of n-hexane at low conversion (< 5%) using as a basis a complex free radical chain mechanism and taking into account H abstraction from propene has been adjusted and compared to the observed product distribution. A reasonably good agreement is found between the computed curves and the experimental results obtained at 693 K and 133 mbar.

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收藏

页码：29 / 40

页数：12

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