VOLCANO PLOTS, HYDRODESULFURIZATION AND SURFACE ATOM PAIR POTENTIALS

被引：29

作者：

BURDETT, JK ^{[1
]}

CHUNG, JT ^{[1
]}

机构：

[1] UNIV CHICAGO,JAMES FRANCK INST,CHICAGO,IL 60637

来源：

SURFACE SCIENCE | 1990年 / 236卷 / 1-2期

关键词：

D O I：

10.1016/0039-6028(90)90754-V

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is shown how a new parameter, the pair potential calculated between two adjacent sulfur atoms of a metal sulfide, correlate with the observed rates of the hydrodesulfurization reaction. The differences between the first row transition metal sulfides and their heavier conjeners is due to the different spin states of the metal. © 1990.

引用

页码：L353 / L357

页数：5

共 10 条

[1] TOPOLOGICAL CONTROL OF THE STRUCTURES OF MOLECULES AND SOLIDS
BURDETT, JK
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (05) : 189 - 194
[2] BURDETT JK, 1987, STRUCT BONDING BERLI, V65, P30
[3] BURDETT JK, UNPUB J AM CHEM SOC
[4] CATALYSIS BY TRANSITION-METAL SULFIDES - THE RELATION BETWEEN CALCULATED ELECTRONIC TRENDS AND HDS ACTIVITY
HARRIS, S
CHIANELLI, RR
[J]. JOURNAL OF CATALYSIS, 1984, 86 (02) : 400 - 412
[5] Johnson K. H., 1973, ADV QUANTUM CHEM, V7, P143
[6] HYDRODESULFURIZATION CATALYSIS BY TRANSITION-METAL SULFIDES
PECORARO, TA
CHIANELLI, RR
[J]. JOURNAL OF CATALYSIS, 1981, 67 (02) : 430 - 445
[7] MODEL HYDRODESULFURIZATION REACTIONS - SATURATED C4S MOLECULES ON MO(110)
ROBERTS, JT
FRIEND, CM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (23) : 7204 - 7210
[8] Weisser O., 1973, SULPHIDE CATALYSTS T
[9] ZONNEVYLLE MC, 1988, SURF SCI, V199, P400
[10] [No title captured]

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