C-2-SYMMETRICAL BIS(AZIRIDINES) - A NEW CLASS OF CHIRAL LIGANDS FOR TRANSITION METAL-MEDIATED ASYMMETRIC-SYNTHESIS

被引：92

作者：

TANNER, D ^{[1
]}

ANDERSSON, PG ^{[1
]}

HARDEN, A ^{[1
]}

SOMFAI, P ^{[1
]}

机构：

[1] LUND UNIV,LUND INST TECHNOL,S-22100 LUND,SWEDEN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 26期

关键词：

CHIRAL LIGANDS; ASYMMETRIC DIHYDROXYLATION; CATALYTIC ASYMMETRIC ALLYLIC SUBSTITUTION; CATALYTIC ASYMMETRIC CYCLOPROPANATION; CATALYTIC ASYMMETRIC AZIRIDINATION;

D O I：

10.1016/S0040-4039(00)60748-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The readily available C-2-symmetric bis(aziridines) I can act as ligands in a variety of asymmetric transformations mediated by transition metals In the best cases, > 95% ee can be obtained.

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收藏

页码：4631 / 4634

页数：4

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