AMINOSELENENYLATION OF ALKENES - SYNTHESES OF BETA-PHENYLSELENO CARBAMATES AND BETA-PHENYLSELENO CYANAMIDES

被引：9

作者：

FRANCISCO, CG ^{[1
]}

HERNANDEZ, R ^{[1
]}

LEON, EI ^{[1
]}

SALAZAR, JA ^{[1
]}

SUAREZ, E ^{[1
]}

机构：

[1] CSIC,INST PROD NAT ORGAN,CARRETERA ESPERANZA 2,E-38206 LA LAGUNA,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 09期

关键词：

D O I：

10.1039/p19900002417

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

β-(Phenylseleno)alkylcarbamates and β-(phenylseleno) alkylcyanamides have been synthesized in good yields by reaction of alkenes with carbamates and cyanamide, respectively, in presence of benzeneselenenyl chloride-silver tetrafluoroborate or N-phenylselenophthalimide-H+. The subsequent reductive or oxidative removal of the phenylseleno group affords alkylcarbamates and alkylcyanamides, and allylic carbamates, cyanamides, and cyanimides.

引用

页码：2417 / 2427

页数：11

共 36 条

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