LOW-TEMPERATURE PARAMAGNETIC ANISOTROPY AND ZERO-FIELD SPLITTING IN HIGH-SPIN (TETRAPHENYLPORPHYRINATO)IRON(III) CHLORIDE

被引：24

作者：

BEHERE, DV

MITRA, S

机构：

[1] TATA INST FUNDAMENTAL RES,CHEM PHYS GRP,BOMBAY 400005,INDIA

[2] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA 2600,ACT,AUSTRALIA

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 06期

关键词：

D O I：

10.1021/ic50196a066

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(Tetraphenylporphyrinato)iron(III) chloride ((TPP)FeCl) is a synthetic iron porphyrin which closely resembles chlorohemin. The ferric ion in (TPP)FeCl is high spin (S = 5/2) with an 6S5/2electronic ground state. The degeneracy of the sextet is partly removed by the combined effect of spin-orbit coupling and axial ligand field, to give three Kramers doublets, namely, Ms= i1/2, ±3/2 and ±5/2. A spin Hamiltonian of the form. © 1979, American Chemical Society. All rights reserved.

引用

页码：1723 / 1724

页数：2

共 20 条

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