ULTRAVIOLET VISIBLE SPECTROSCOPIC STUDIES ON MANGANESE AND RHENIUM OXIDE FLUORIDES IN LOW-TEMPERATURE MATRICES

被引：18

作者：

BRISDON, AK ^{[1
]}

HOLLOWAY, JH ^{[1
]}

HOPE, EG ^{[1
]}

TOWNSON, PJ ^{[1
]}

LEVASON, W ^{[1
]}

OGDEN, JS ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 11期

关键词：

D O I：

10.1039/dt9910003127

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five high-oxidation-state metal oxide fluorides, MnO3F, ReO3F, ReO2F3, ReOF5 and ReOF4 have been isolated as molecular species in inert-gas matrices at low temperatures, and studied by IR and UV/VIS spectroscopy. In particular, the electronic spectra are described and the principal charge-transfer bands assigned using the optical electronegativity model. This suggested that a new value for chi-opt(F-) of 3.6 is appropriate for transition-metal oxide fluorides.

引用

页码：3127 / 3132

页数：6

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