THERMAL REVERSIBILITY OF THE PHOTO-CHEMICAL DI-PI-METHANE REARRANGEMENT OF BICYCLO[2,2,2]OCTADIENONES - CONFIRMATION OF REGIOSPECIFICITY AND STEROCHEMISTRY BY X-RAY STRUCTURE ANALYSES

被引:5
作者
BECKER, HD
RUGE, B
SKELTON, BW
WHITE, AH
机构
[1] UNIV WESTERN AUSTRALIA,DEPT PHYS & INORGAN CHEM,NEDLANDS 6009,W AUSTRALIA,AUSTRALIA
[2] UNIV GOTHENBURG,GOTHENBURG,SWEDEN
关键词
D O I
10.1071/CH9791231
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Thermolysis of the tricyclic photo-isomer obtained by di-π-methane rearrangement of a t-butyl- substituted bicyclo[2, 2, 2]octadienone regenerates a new bicyclo[2, 2, 2]octadienone in which the oxo- substituted C2-bridge has undergone a 1, 3-migration. The structures of the three isomers involved were established by X-ray analyses. © 1979, CSIRO. All rights reserved.
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页码:1231 / 1240
页数:10
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