DIELECTRIC ANALYSIS OF AN EPOXY-RESIN DURING CROSS-LINKING

被引:59
作者
BUTTA, E
LIVI, A
LEVITA, G
ROLLA, PA
机构
[1] POLITECN MILAN,DEPT CHEM ENGN & IND CHEM,I-20133 MILAN,ITALY
[2] UNIV PISA,DEPT PHYS,I-56100 PISA,ITALY
关键词
DIELECTROMETRY; EPOXY; CROSS-LINKING;
D O I
10.1002/polb.1995.090331610
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The dielectric behavior of an epoxide/ethylenediamine formulation has been studied during cross-linking in the frequency range 10(3)-10(10) Hz at 25 degrees C and 70 degrees C. Dielectric data were collected both in the frequency and in the time domains and analyzed in terms of a combination of two Havriliak-Negami functions. A complete description of the evolution of the relaxation parameters during the reaction was obtained. The nature of the information yielded by dielectrometry on the dynamics of the system is discussed. (C) 1995 John Wiley & Sons, Inc.
引用
收藏
页码:2253 / 2261
页数:9
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