REACTION OF DILITHIOOXIMES WITH EPOXIDES - NOVEL ROUTE TO 1,4-DIKETONES AND ITS APPLICATION TO DIHYDROJASMONE SYNTHESIS

被引：10

作者：

BELLASSOUED, M

DARDOIZE, F

GAUDEMAR, M

机构：

[1] Laboratoire de Synthèse Organométallique Université Pierre et Marie Curie, F-75230 Paris Cedex 05, Bâtiment F

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 177卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)92329-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dilithiooximes react with epoxides at room temperature in THF to give, after neutral hydrolysis, the corresponding γ-hydroxyoximes. These latter can be deoximated and oxidized to lead to the expected 1,4-diketones. This approach is successfully applied to the dihydrojasmone synthesis. © 1979.

引用

页码：35 / 38

页数：4

共 10 条

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