(ETA-5-CYCLOPENTADIENYL)MANGANESE DICARBONYL ETA-3-ALLYL CATIONS

被引：6

作者：

ROSAN, AM

ROMANO, DM

机构：

[1] Department of Chemistry, Drew University, Madison

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1021/om00118a022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A range of Mn(III) π-allyl cations of the form (η5-cyclopentadienyl)manganese dicarbonyl-η3-allyl+PF6- has been prepared and characterized by IR and1H NMR. These compounds are available through two convenient synthetic avenues involving coordination and subsequent dehydration of allylic alcohols or protonation of 1,3-dienes. © 1990, American Chemical Society. All rights reserved.

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页码：1048 / 1052

页数：5

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