SYNTHETIC METHODS .14. FRAGMENTATIONAL APPROACH TO MACROLIDES - (5-E, 8-Z)-6-METHYL-5,8-UNDECADIEN-11-OLIDE

被引：39

作者：

STERNBACH, D

SHIBUYA, M

JAISLI, F

BONETTI, M

ESCHENMOSER, A

机构：

[1] SWISS FED INST TECHNOL,ORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

[2] TOKUSHIMA UNIV,FAC PHARMACEUT SCI,TOKUSHIMA 770,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 08期

关键词：

D O I：

10.1002/anie.197906341

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Decarboxylative double fragmentation of type A is the key step in the synthesis of the unsaturated lactone 2 from the amidinium salt 1. The diastereomer of 1 also gives 2. The isomeric lactone 3 can be obtained analogously from diastereomeric amidinium salts. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：634 / 636

页数：3

共 36 条

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