SPECTROELECTROCHEMISTRY OF METALLOPORPHYRINS

被引：17

作者：

KADISH, KM

MU, XH

机构：

[1] Department of Chemistry, University of Houston, Houston

来源：

PURE AND APPLIED CHEMISTRY | 1990年 / 62卷 / 06期

关键词：

D O I：

10.1351/pac199062061051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three examples have been selected to illustrate the application and benefits of thin-layer spectroelectrochemistry for monitoring metalloporphyrin redox reactions. These examples show how FTIR, UV-visible and ESR spectroelectrochemical techniques can be combined to monitor the site of oxidation/reduction, the fate of the bound diatomic molecule after electron transfer, the type of π cation radical generated and the spectral properties of a product formed in reactions between an electroreduced porphyrin and the methylene chloride solvent. © 1990 IUPAC

引用

收藏

页码：1051 / 1054

页数：4

相关论文

共 17 条

[1] A SIMPLIFIED SYNTHESIS FOR MESO-TETRAPHENYLPORPHIN [J].

ADLER, AD ;

LONGO, FR ;

FINARELLI, JD ;

GOLDMACH.J ;

ASSOUR, J ;

KORSAKOF.L .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (02) :476-+

[2] COBALT(II) NITROSYL CATION RADICALS OF PORPHYRINS, CHLORINS, AND ISOBACTERIOCHLORINS - MODELS FOR NITRITE AND SULFITE REDUCTASES AND IMPLICATIONS FOR A1U HEME RADICALS [J].

FUJITA, E ;

CHANG, CK ;

FAJER, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (25) :7665-7669

[3] ELECTRON-SPIN-RESONANCE SPECTRA OF 6-COORDINATE COBALT(III) TETRAPHENYLPORPHYRIN CATION RADICALS GENERATED BY ELECTROCHEMICAL OXIDATION .2. AXIAL LIGAND AND SOLVENT EFFECTS [J].

ICHIMORI, K ;

OHYANISHIGUCHI, H ;

HIROTA, N ;

YAMAMOTO, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (02) :623-630

[4] THE CONSTRUCTION AND UTILIZATION OF A SIMPLE LIGHT-TRANSPARENT FTIR SPECTROELECTROCHEMICAL CELL WITH THIN-LAYER CHAMBER [J].

KADISH, KM ;

MU, XH ;

LIN, XQ .

ELECTROANALYSIS, 1989, 1 (01) :35-41

[5] CHLORIDE-BINDING REACTIONS AND ELECTROCHEMISTRY OF (TPP)COII AND (TPP)COIIICL IN DICHLOROMETHANE [J].

KADISH, KM ;

LIN, XQ ;

HAN, BC .

INORGANIC CHEMISTRY, 1987, 26 (25) :4161-4167

[6] A REINVESTIGATION OF SILVER PORPHYRIN ELECTROCHEMISTRY - REACTIONS OF AG(III), AG(II), AND AG(I) [J].

KADISH, KM ;

LIN, XQ ;

DING, JQ ;

WU, YT ;

ARAULLO, C .

INORGANIC CHEMISTRY, 1986, 25 (18) :3236-3242

[7]

KADISH KM, 1982, INORG CHEM, V21, P3614, DOI 10.1021/ic00140a007

[8] THE ELECTROCHEMISTRY OF METALLOPORPHYRINS IN NONAQUEOUS MEDIA [J].

KADISH, KM .

PROGRESS IN INORGANIC CHEMISTRY, 1986, 34 :435-605

[9] MICROVOLTAMMETRY AND INSITU FTIR, ELECTRON-SPIN-RESONANCE, AND UV-VISIBLE SPECTROELECTROCHEMICAL STUDIES OF (TPP)CO(NO) OXIDATION REDUCTION IN DICHLOROMETHANE [J].

KADISH, KM ;

MU, XH ;

LIN, XQ .

INORGANIC CHEMISTRY, 1988, 27 (08) :1489-1492

[10] VACUUM-TIGHT THIN-LAYER SPECTROELECTROCHEMICAL CELL WITH A DOUBLET PLATINUM GAUZE WORKING ELECTRODE [J].

LIN, XQ ;

KADISH, KM .

ANALYTICAL CHEMISTRY, 1985, 57 (07) :1498-1501