SYNTHESES AND PROPERTIES OF UV-AUTOCURABLE BTDA-BASED POLYESTER MULTIACRYLATES .2. EFFECT OF POLYOL TYPE AND REACTIVE MONOMER

被引：13

作者：

CHIANG, WY

CHAN, SC

机构：

[1] Department of Chemical Engineering, Tatung Institute of Technology, Taipei, 10415, 40 Chungshan North Road

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1990年 / 179卷

关键词：

D O I：

10.1002/apmc.1990.051790105

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Several families of UV‐autocurable benzophenone tetracarboxylic dianhydride (BTDA)‐based polyester multiacrylate oligomers containing pendant glycidyl methacrylate (GMA) were synthesized and the effects of acrylic functionality and polyol type on their properties were investigated. The obtained autocurable oligomers possess good pot life and are cured rapidly when exposed to ultraviolet (UV) radiation without the addition of photoinitiator or photosensitizer. Different polyols were used to obtain wide range properties of cured multiacrylate oligomers with a glass transition temperature (Tg) range of 84–130°C. A further modification of the multiacrylate oligomers was obtained by mixing them with reactive monomers having different molecular structure and methacrylic functionality. © 1990 Hüthig & Wepf Verlag, Basel

引用

页码：57 / 75

页数：19

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[1] SYNTHESIS OF POLYMER MATERIALS BY LOW-ENERGY ELECTRON-BEAM .3. EFFECTS OF POLYMERIZATION TEMPERATURE IN EB SOLID-STATE POLYMERIZATION OF SEMICRYSTALLINE URETHANE-ACRYLATE FILM [J].