ASSOCIATIVE EXCHANGE OF A GUANOSINE LIGAND ON TRIARYLPHOSPHINE-GOLD(I) COMPLEXES

被引：2

作者：

KOMIYA, S

NAKADA, K

HIRATA, M

FUKUOKA, A

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 03期

关键词：

D O I：

10.1246/cl.1993.457

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of nitrato(triarylphosphine)gold(I) complexes [Au(PR3)(NO3)] with nucleosides such as guanosine (Guo), adenosine (Ado), and cytidine (Cyd) give new nucleoside-containing gold(I) complexes, [Au(PR3)(Nuc)](NO3) (R = Ph, o-anisyl, p-anisyl; Nuc = Guo, Ado, Cyd) in DMSO-d6. NMR study reveals that the coordinated Guo ligand rapidly exchanges with free Guo by an associative mechanism.

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页码：457 / 460

页数：4

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