MOLYBDENUM-ALLYLOXO AND MOLYBDENUM-ALLYLAMIDO COMPLEXES AS MODELS FOR THE CATALYTIC SURFACE INTERMEDIATES OF THE OXIDATION OF PROPENE TO ACROLEIN AND ACRYLONITRILE

被引：14

作者：

BELGACEM, J ^{[1
]}

KRESS, J ^{[1
]}

OSBORN, JA ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,INST LE BEL,CHIM METAUX TRANSIT & CATALYSE LAB,CNRS,URA 424,F-67070 STRASBOURG,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 14期

关键词：

D O I：

10.1039/c39930001125

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molybdenum(VI)-allyloxo and -allylamido complexes with oxo or imido ancillary ligands are synthesized and shown to decompose under mild conditions to acrolein and allylideneamine, respectively, with dimeric Mo(V) compounds as the other products; the analogies between these results and those proposed for the mechanism of the oxidation and ammoxidation of propene are discussed.

引用

页码：1125 / 1127

页数：3

共 30 条

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