A GENERAL-SYNTHESIS OF NEW DITHIOLETHIONE DERIVATIVES - 5-(1-HYDROXYIMINO ALKYL)-1,2-DITHIOLE-3-THIONES AND 5-ACYL-1,2-DITHIOLE-3-THIONES

被引：13

作者：

ABAZID, M ^{[1
]}

BERTRAND, HO ^{[1
]}

CHRISTEN, MO ^{[1
]}

BURGOT, JL ^{[1
]}

机构：

[1] SOLVAY PHARMA,THERAPEUT MODERNE LABS,F-92151 SURESNES,FRANCE

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 88卷 / 1-4期

关键词：

5-ALKYL-1,2-DITHIOLE-3-THIONES; DISULFIDES; 5-(1-HYDROXYIMINOALKYL)-1,2-DITHIOLE-3-THIONES;

D O I：

10.1080/10426509408036922

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of 5-(1-hydroxyiminoalkyl)-1,2-dithiole-3-thiones by allowing 5-alkyl-1,2-dithiole-3-thiones to react with an excess of sodium nitrite in acetic acid and by reducing highly insoluble intermediate disulfides by sodium sulfide in a DMSO-water mixture is described. 5-(1-hydroxyimino)-1,2-dithiole-3-thiones are easily transformed into 5-acyl-1,2-dithiole-3-thiones. All yields are quite satisfactory.

引用

页码：195 / 206

页数：12

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