BOND-CLEAVAGE REACTIONS IN OXYGEN AND NITROGEN-HETEROCYCLES BY A RHODIUM PHOSPHINE COMPLEX

被引：40

作者：

JONES, WD

DONG, LZ

MYERS, AW

机构：

[1] Department of Chemistry, University of Rochester, Rochester

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 02期

关键词：

D O I：

10.1021/om00002a037

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of (C(5)Me(5))Rh(PMe(3))PhH with furan, 2,5-dimethylfuran, 2,3-dihydrofuran, dibenzofuran, pyrrole, 1-methylpyrrole, 2,5-dimethylpyrrole, 1,2,5-trimethylpyrrole, carbazole, 9-methylcarbazole, pyrrolidine, pyridine, 3,5-lutidine, 2,4,6-collidine, pyrazole, 3-methylpyrazole, and piperidine have been investigated. While the oxygen heterocycles give only C-H activation, the nitrogen heterocycles yield C-H and N-H insertion products. The chloro derivative (C(5)Me(5))Rh(PMe(3))[2-(1-methylpyrrole)]Cl was found to crystallize in the monoclinic space group C2/c with a = 13.753 (6) Angstrom, b = 9.665 (5) Angstrom, c = 30.14 (2) Angstrom, beta = 99.77 (5)degrees, Z = 8, and V = 3949 (4.1) Angstrom(3) while (C(5)Me(5))Rh(PMe(3))[2-(3,5-lutidine)]Cl was found to crystallize in the monoclinic space group P2(1)/c with a = 14.976 (8) Angstrom, b = 8.613 (5) Angstrom, c = 17.12 (2) Angstrom, beta = 101.90 (6)degrees, Z = 4, and V = 2160 (5.2) Angstrom(3).

引用

页码：855 / 861

页数：7

共 38 条

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