ELECTROCHEMICAL EXFOLIATION OF GRAPHITE IN TRIFLUOROACETIC MEDIA

被引：24

作者：

BOURELLE, E

DOUGLADE, J

METROT, A

机构：

[1] Laboratoire d'Electrochimie et Chimie du Solide, Faculté des Sciences

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1994年 / 244卷

关键词：

D O I：

10.1080/10587259408050109

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Electrochemical anodization of graphite in trifluoroacetic media, when performed with a sufficiently high current density, leads to exfoliation of graphite. This reaction has been studied using X-ray diffractometry, A.C Impedance Spectroscopy and gas analysis in various experimental conditions. A mechanism is proposed based on a Kolbe reaction occuring in the interlayer spacings.

引用

页码：227 / 232

页数：6

共 11 条

[1] GRAPHITE SALTS WITH PERFLUOROALKANESULFONIC ACIDS AND ALKANESULFONIC ACIDS [J].