TRIMESITYLGERMYLLITHIUM - SYNTHESIS AND REACTIVITY

被引：7

作者：

CASTEL, A

RIVIERE, P

SATGE, J

KO, YH

DESOR, D

机构：

[1] Laboratoire de Chimie des Organominéraux, URA 477 du CNRS, Université Paul Sabatier, 31062 Toulouse Cedex

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 397卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)85308-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new organogermyllithium Mes3GeLi has been prepared in good yield by hydrogermolysis reaction of t-butyllithium in THF. The bulky group favours stabilization in the form of the THF complex. Mes3GeLi has been characterized by alkylation reaction with MeI. Some metalation reactions are reported. They lead to the formation of unsymmetrical or symmetrical organogermylmercuric compounds and also of new dissymetrical digermanes by a classic nucleophilic reaction. In contrast, the reaction of Mes3GeLi with benzoyl chloride is more complex and apparently proceeds by a single electron transfer process. © 1990.

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页码：7 / 15

页数：9

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