CHEMICAL AND ELECTROCHEMICAL REDUCTION OF DISELENIDE DICATION SALT, 1,5-DISELENONIABICYCLO[3.3.0]OCTANE BIS(HEXAFLUOROPHOSPHATE)

被引：11

作者：

FUJIHARA, H ^{[1
]}

AKAISHI, R ^{[1
]}

NAKAMURA, A ^{[1
]}

FURUKAWA, N ^{[1
]}

机构：

[1] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(00)97068-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of the diselenide dication salt, 1,5-diselenoniabicyclo[3.3.0]octane bis(hexafluorophosphate) (1) with 1,5-diselenacyclooctane (2) gave the corresponding cation radical by single-electron transfer. The dication salt 1 was reduced upon treatment with fluorenyl-lithium, Na2S, NaBH4; it did not deprotonate. The cyclic voltammetry of 1 shows the reversible reduction peak at remarkably low reduction potential. © 1990.

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页码：6375 / 6378

页数：4

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