ANTI-FERROMAGNETIC COMPLEXES INVOLVING METAL-METAL BONDS .1. SYNTHESIS AND MOLECULAR-STRUCTURE OF AN ANTI-FERROMAGNETIC DIMER WITH A CR-CR BOND

被引：66

作者：

PASYNSKII, AA ^{[1
]}

EREMENKO, IL ^{[1
]}

RAKITIN, YV ^{[1
]}

NOVOTORTSEV, VM ^{[1
]}

KALINNIKOV, VT ^{[1
]}

ALEKSANDROV, GG ^{[1
]}

STRUCHKOV, YT ^{[1
]}

机构：

[1] ACAD SCI USSR,INST ORGANOELEMENT CPDS,MOSCOW V-71,USSR

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 165卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81135-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The binuclear complex (C5H5)2Cr2(S)(SCMe3)2 was prepared by refluxing a solution of chromocene and t-butylmercaptane in heptane. The structure of the product was determined by single crystal X-ray diffraction. The chronium atoms are linked by a sulphide bridge (SCr 2.24 Å;, <CrSCr 74.1° and two SCMe3 bridges (CrS 2.38 Å;, <CrSCr 68.3-69.3°). The two cyclopentadienyl ligands (CC 1.41 Å;, CrC 2.23 Å;) are in apical positions, their ring planes being parallel to each other. The complex is an antiferromagnet (-2J cm-1) despite the small CrSCr angles and short chromiumchromium distance (2.689 Å;) indicative of strong CrCr bonding. © 1979.

引用

页码：57 / 64

页数：8

共 31 条

[1] UNUSUAL STRUCTURAL AND MAGNETIC-RESONANCE PROPERTIES OF DICYCLOPENTADIENYLHEXACARBONYLDICHROMIUM [J].

ADAMS, RD ;

COLLINS, DE ;

COTTON, FA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (03) :749-754

[2]

ANDRIANOV VG, 1969, ZH STRUKT KHIM, V10, P1145

[3] STRUCTURE AND NATURE OF BONDING OF [C2H5SFE(CO)3]2 [J].

DAHL, LF ;

WEI, CH .

INORGANIC CHEMISTRY, 1963, 2 (02) :328-&

[4]

DANGE IG, 1975, J CHEM SOC CHEM COMM, P762

[5]

DREW J, 1974, J CHEM SOC CHEM COMM, P843

[6] CRYSTAL STRUCTURE OF DI-MU-PHENYLTHIO-BIS(CYCLOPENTADIENYL-CARBONYLIRON) AT -160 DEGREES [J].

FERGUSON, G ;

HANNAWAY, C ;

ISLAM, KMS .

CHEMICAL COMMUNICATIONS, 1968, (19) :1165-&

[7] COPPER(2) COMPLEXES WITH SUBNORMAL MAGNETIC MOMENTS [J].

KATO, M ;

JONASSEN, HB ;

FANNING, JC .

CHEMICAL REVIEWS, 1964, 64 (02) :99-&

[8]

KEPERT DL, 1975, COMPOUNDS TRANSITION, P198

[9]

KING R, 1965, ORGANOMETALLIC SYNTH, V1

[10]

KIRILLOVA NI, 1972, ZH STRUKT KHIM, V13, P880

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