NANOSTRUCTURAL-PROPERTY RELATIONS IN COMPLEX LEAD PEROVSKITES

被引：342

作者：

RANDALL, CA

BHALLA, AS

机构：

[1] Materials Research Laboratory, The Pennsylvania State University, University Park, PA

来源：

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1990年 / 29卷 / 02期

关键词：

Dielectric properties; Electron microscopic study; Model for relaxor behavior; Nanocomposite; Relaxor materials;

D O I：

10.1143/JJAP.29.327

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

From transmission electron microscopy studies on several complex lead perovskite compounds Pb(B'B'')O3, and their solid solutions a classification can be obtained based on B-cation order. This classification divides the complex lead perovskites into three subgroups; random occupation or disordered, nanoscale or short coherent long-range order and long coherent long-range order of B-site cations. A correlation between the nanoscale B-site order and relaxor on glassy ferroelectric behavior is found in these lead perovskites. An hypothesis is suggested which relates 0-3 polar connectivity to 0-3 order-disorder connectivity. This hypothesis is discussed with relation to present theories [G. A. Smolenskii: J. Phys. Soc. Jpn. (1970) Suppl., p. 26, L. E. Cross: Ferroelectrics 76 (1987) 241, T. L. Renieke and K. L. Ngai: Solid State Commun. 18 (1973) 1543] and reported experimental results of the perovskite relaxor ferroelectrics. © 1990 The Japan Society of Applied Physics.

引用

页码：327 / 333

页数：7

共 34 条

[1]

[Anonymous], 1969, STRUCTURE PROPERTIES

[2]

BOKOV VA, 1961, FIZ TVERD TELA, V3, P613

[3]

BRIXEL W, 1984, FERROELECTRICS, V55, P181

[4] THE CHARACTERIZATION OF HIGH-TEMPERATURE SOLUTION-GROWN SINGLE-CRYSTALS OF PB(FE1/2NB1/2)O3 [J].