SYNTHESIS AND CHARACTERIZATION OF THE 1ST WATER-SOLUBLE CLOSELY INTERSPACED COFACIAL PORPHYRIN DIMER

被引：28

作者：

KARAMAN, R ^{[1
]}

BRUICE, TC ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 11期

关键词：

D O I：

10.1021/jo00011a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first closely spaced quadruply bridged water-soluble cofacial dimer (5) was successfully synthesized by the reaction of porphyrin 2 with sulfonamide 3 followed by N-methylation with methyl iodide. The conformations of 5 and its precursor 4 are largely dependent on the solvent, and the solvent effect is inhibited by protonation or metalation of the porphyrin cores.

引用

页码：3470 / 3472

页数：3

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