MOLECULAR-INTERACTIONS BETWEEN ORGANIZED, SURFACE-CONFINED MONOLAYERS AND VAPOR-PHASE PROBE MOLECULES - HYDROGEN-BONDING INTERACTIONS

被引：130

作者：

SUN, L ^{[1
]}

KEPLEY, LJ ^{[1
]}

CROOKS, RM ^{[1
]}

机构：

[1] UNIV NEW MEXICO,DEPT CHEM,ALBUQUERQUE,NM 87131

来源：

LANGMUIR | 1992年 / 8卷 / 09期

关键词：

D O I：

10.1021/la00045a006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of controlled hydrogen-bonding interactions between a self-assembled monolayer and vapor-phase probe molecules is reported. FTIR-external reflectance spectroscopic data and ellipsometric experiments confirm that 1-alkanoic acids containing 10 or more carbons specifically adsorb to a surface-confined monolayer of an acid-functionalized mercaptan. 3-mercaptopropionic acid, through hydrogen-bonding interactions.

引用

页码：2101 / 2103

页数：3

共 21 条

[1] FORMATION OF MONOLAYER FILMS BY THE SPONTANEOUS ASSEMBLY OF ORGANIC THIOLS FROM SOLUTION ONTO GOLD [J].