KINETICS OF CATALYTIC TRANSFER HYDROGENATION OF SOYBEAN OIL IN MICROWAVE AND THERMAL FIELD

被引：20

作者：

LESKOVSEK, S ^{[1
]}

SMIDOVNIK, A ^{[1
]}

KOLOINI, T ^{[1
]}

机构：

[1] UNIV LJUBLJANA,DEPT CHEM & CHEM TECHNOL,LJUBLJANA 61000,SLOVENIA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 24期

关键词：

D O I：

10.1021/jo00103a041

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The influence of microwave irradiation on the reaction kinetics of the soybean oil catalytic transfer hydrogenation was investigated. The kinetic constants were determined experimentally in a microwave field and are compared with water bath measurements at comparable bulk temperatures. In both the microwave and thermal fields all hydrogenation reactions obey first-order kinetics with respect to the fatty acids. The reaction rates were up to 8 times greater using microwave heating than with conventional heating at the same temperature.

引用

页码：7433 / 7436

页数：4

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