CONTACT SHIFT STUDIES OF SQUARE-PLANAR COMPLEX BIS(DITHIOACETYLACETONATO)COBALT(II)

被引：19

作者：

FITZGERALD, RJ

BRUBAKER, GR

机构：

[1] Department of Chemistry, Illinois Institute of Technology, Chicago

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 11期

关键词：

D O I：

10.1021/ic50081a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, magnetic moment, and the proton nmr contact shift data for the square-planar complex bis(dithioacetylacetonato) cobalt(II) are reported. Our results indicate that the unpaired electron resides in the dz2 orbital in agreement with some previous studies on square-planar cobalt(II) complexes. Possible electron delocalization mechanisms and dipolar contributions to the observed contact shifts are discussed. © 1969, American Chemical Society. All rights reserved.

引用

页码：2265 / +

页数：1

共 21 条

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