POLARIZED FTIR SPECTRA OF ADAMANTANOL DERIVATIVES .2. 2-PHENYLADAMANTAN-2-OL

被引：3

作者：

BARAN, J ^{[1
]}

HNAT, MW ^{[1
]}

LUTZ, ETG ^{[1
]}

VANDERMAAS, JH ^{[1
]}

机构：

[1] STATE UNIV UTRECHT,ANALYT CHEM LAB,3522 AD UTRECHT,NETHERLANDS

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1990年 / 237卷

关键词：

D O I：

10.1016/0022-2860(90)80152-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The polarized FTIR-spectra of the 2-phenyladamantan-2-ol (PA2) single crystal and powder spectra of the PA2 and deuterated PA2-d samples have been investigated. The results indicate that the OH groups are involved in weak OH⋯O hydrogen bonds. The hydrogen bond vibrations are identified at 3375 [ν(OH)], 1395 [δ(OH)] and about 600 cm-1 [γ(OH)] and discussed in relation to the selection rules and to the oriented gas model approximation. Davydov splitting of the out-of-plane deformation mode γ(OH) is observed. The other internal vibrations in the range 4000-400 cm-1 are tentatively assigned. © 1990.

引用

页码：355 / 365

页数：11

共 27 条

[1] STRUCTURE OF 1-PHENYLCYCLOHEXANOL
AHMED, FR
HUBER, CP
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1981, 37 (OCT): : 1874 - 1877
[2] AMOUREUX JP, 1979, CRYST STRUCT COMMUN, V8, P449
[3] SPECTROSCOPIC AND THERMODYNAMIC STUDIES OF MOLECULAR CRYSTALS .1. INTERNAL VIBRATIONS OF ADAMANTANE IN PLASTIC PHASE
BAILEY, RT
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1971, A 27 (08): : 1447 - &
[4] POLARIZED INFRARED AND RAMAN-SPECTRA OF CSHSEO4 AND CSDSEO4 SINGLE-CRYSTALS
BARAN, J
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1987, 162 (3-4) : 229 - 245
[5] POLARIZED INFRARED AND RAMAN-SPECTRA OF A CSHSO4 SINGLE-CRYSTAL
BARAN, J
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1987, 162 (3-4) : 211 - 228
[6] BARAN J, UNPUB
[7] BARAN JR, IN PRESS
[8] CYVIN SJ, 1972, MOL STRUCTURES VIBRA, P363
[9] GRISHINA EN, 1980, ZH PRIKL SPECTROSC, V32, P664
[10] PHASE-TRANSITIONS AND MOLECULAR MOTIONS IN ADAMANTANE DERIVATIVES - 1-ADAMANTANOL
HARVEY, PD
GILSON, DFR
BUTLER, IS
[J]. CANADIAN JOURNAL OF CHEMISTRY, 1987, 65 (08) : 1757 - 1760

← 1 2 3 →