ELECTROCHEMICAL-BEHAVIOR OF VARIOUS POLYANILINE MORPHOLOGIES IN NONAQUEOUS ELECTROLYTES

被引：8

作者：

MICHAELSON, JC

MCEVOY, AJ

GRATZEL, M

机构：

[1] Institut de Chimie Physique II, Ecole Polytechnique Fédérale de Lausanne, Lausanne

来源：

SYNTHETIC METALS | 1993年 / 55卷 / 2-3期

关键词：

D O I：

10.1016/0379-6779(93)90285-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrochemical behavior of polyaniline and structurally modified polyaniline has been studied in various nonaqueous media including solvents such as acetonitrile and propylene carbonate, together with LiClO4 or other salts. Employing special chronopotentiometric techniques on various polyaniline samples, anticipated battery performance has been determined; such simulations have enabled us to investigate the effects of extensive charging of polymer films as limited by switching potentials. Preliminary results, including quantitative measurements of electrochemical reversibility and long-term degradation, are reported here.

引用

页码：1564 / 1569

页数：6

共 13 条

[1]

CHIANG CK, 1977, PHYS REV LETT, V39, P187

[2]

DESILVESTRO J, 1991, PSI GENERAL ENERGY T, P9

[3] SPECTROELECTROCHEMICAL STUDY OF POLYANILINE VERSUS POTENTIAL IN THE EQUILIBRIUM STATE [J].

GENIES, EM ;

LAPKOWSKI, M .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 220 (01) :67-82

[4] CHRONOPOTENTIOMETRIC STUDIES OF POLYANILINE FILMS [J].

KALAJI, M ;

NYHOLM, L ;

PETER, LM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 325 (1-2) :269-284

[5]

KIESS H, 1986, 13TH P INT C EL CONT

[6] MODIFICATION OF GROWTH-RATE AND STRUCTURE OF ELECTROPOLYMERISED ANILINE BY SODIUM POLYVINYL SULFONATE [J].

KURAMOTO, N ;

MICHAELSON, JC ;

MCEVOY, AJ ;

GRATZEL, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (21) :1478-1480

[7] POLYANILINE - INTERCONVERSION OF METALLIC AND INSULATING FORMS [J].

MACDIARMID, AG ;

CHIANG, JC ;

HALPERN, M ;

HUANG, WS ;

MU, SL ;

SOMASIRI, NLD ;

WU, WQ ;

YANIGER, SI .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 121 (1-4) :173-180

[8] MORPHOLOGY OF PARAPHENYLENEDIAMINE-ANILINE CONDUCTING COPOLYMERS [J].

MAILHERANDOLPH, C ;

MCEVOY, AJ .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1989, 93 (08) :905-908

[9] MORPHOLOGY AND GROWTH-RATE OF POLYANILINE FILMS MODIFIED BY SURFACTANTS AND POLYELECTROLYTES [J].

MICHAELSON, JC ;

MCEVOY, AJ ;

KURAMOTO, N .

REACTIVE POLYMERS, 1992, 17 (02) :197-206

[10]

MIZUMOTO M, 1989, SYNTHETIC MET, V28, pC639, DOI 10.1016/0379-6779(89)90584-5

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