SELECTIVITY IN REDOX-SWITCHED CALIX[4]ARENE CATIONOPHORES - ELECTROCHEMICAL DETECTION OF A CONFORMATIONAL CHANGE ON CATION-BINDING

被引：31

作者：

BETHELL, D ^{[1
]}

DOUGHERTY, G ^{[1
]}

CUPERTINO, DC ^{[1
]}

机构：

[1] ZENECA SPECIALITIES PLC,MANCHESTER M9 8ZS,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期

关键词：

D O I：

10.1039/c39950000675

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three 4-tert-butylcalix[4]arenes bearing a 1,8-bis(ethyleneoxy)anthraquinone bridge; between alternate phenolic oxygen atoms, on one-electron reduction, show enhanced binding of alkali-metal cations with selectivities dependent upon the groups attached at the other phenolic oxygens; for one of the compounds, binding of potassium but not sodium is accompanied by a conformational change of the calixarene from cane to partial cone.

引用

页码：675 / 676

页数：2

共 19 条

[1] SYNTHESIS, AND X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF A NOVEL MACROBICYCLIC LIGAND - CROWNED PARA-TERT-BUTYL-CALIX[4]ARENE
ALFIERI, C
DRADI, E
POCHINI, A
UNGARO, R
ANDREETTI, GD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (19) : 1075 - 1077
[2] THE PREPARATION AND PROPERTIES OF A NEW LIPOPHILIC SODIUM SELECTIVE ETHER ESTER LIGAND DERIVED FROM PARA-TERT-BUTYLCALIX(4)ARENE
ARDUINI, A
POCHINI, A
REVERBERI, S
UNGARO, R
ANDREETTI, GD
UGOZZOLI, F
[J]. TETRAHEDRON, 1986, 42 (07) : 2089 - 2100
[3] SYNTHESIS, X-RAY CRYSTAL-STRUCTURES, AND CATION-BINDING PROPERTIES OF ALKYL CALIXARYL ESTERS AND KETONES, A NEW FAMILY OF MACROCYCLIC MOLECULAR RECEPTORS
ARNAUDNEU, F
COLLINS, EM
DEASY, M
FERGUSON, G
HARRIS, SJ
KAITNER, B
LOUGH, AJ
MCKERVEY, MA
MARQUES, E
RUHL, BL
SCHWINGWEILL, MJ
SEWARD, EM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (23) : 8681 - 8691
[4] BAKKER WII, 1994, J AM CHEM SOC, V116, P123
[5] METAL, AMMONIUM AND ALKYL AMMONIUM CATION RECOGNITION BY A NOVEL CALIX[4]ARENEDIQUINONE CROWN-ETHER
BEER, PD
CHEN, Z
DREW, MGB
GALE, PA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (19) : 2207 - 2208
[6] NEW METAL CATION-SELECTIVE IONOPHORES DERIVED FROM CALIXARENES
CHANG, SK
CHO, I
[J]. CHEMISTRY LETTERS, 1984, (04) : 477 - 478
[7] CALIXARENE-BASED AMIDE IONOPHORES FOR GROUP-IIA METAL-CATIONS
CHANG, SK
KWON, SK
CHO, I
[J]. CHEMISTRY LETTERS, 1987, (05) : 947 - 948
[8] NEW METAL CATION-SELECTIVE IONOPHORES DERIVED FROM CALIXARENES - THEIR SYNTHESES AND ION-BINDING PROPERTIES
CHANG, SK
CHO, I
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (02): : 211 - 214
[9] UNUSUAL 1-2 LIGAND-METAL COMPLEX-FORMATION BETWEEN AN ANTHRAQUINONE CRYPTAND AND LI+
CHEN, ZH
SCHALL, OF
ALCALA, M
LI, Y
GOKEL, GW
ECHEGOYEN, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (02) : 444 - 451
[10] ELECTROCHEMICAL-BEHAVIOR AND COMPLEXATION WITH ALKALI-METAL CATIONS OF REDUCED SYNTHETIC MACROCYCLIC-COMPOUNDS OF THE CROWN-ETHER TYPE ATTACHED TO AN ANTHRAQUINONE UNIT
COSTA, JMC
JEYASHRI, B
BETHELL, D
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 351 (1-2): : 259 - 269

← 1 2 →