SYNTHESIS, STRUCTURAL AND CONFORMATIONAL STUDY OF 6-HYDROXY (OR ACYLOXY) DERIVATIVES OF THE 1,3-DIMETHYL-1,3-DIAZONIATRICYCLO[3.3.1.1/3-7]DECANE SYSTEM

被引：9

作者：

FERNANDEZ, MJ ^{[1
]}

GALVEZ, E ^{[1
]}

LORENTE, A ^{[1
]}

CAMUNAS, JA ^{[1
]}

SANZ, J ^{[1
]}

FONSECA, I ^{[1
]}

机构：

[1] CSIC,INST ROCASOLANO,DEPT RAVOS X,E-28006 MADRID,SPAIN

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1990年 / 27卷 / 05期

关键词：

D O I：

10.1002/jhet.5570270533

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,3‐Dimethyl‐1,3‐diazoniatricyclo[3.3.1.13–7]decan‐6‐ol, and his p‐chlorobenzoxy and diphenylacetoxy derivatives have been synthesized and studied by 1H and 13C nmr spectroscopy. The crystal structure of the alcohol 2a has been determined by X‐ray diffraction. Each ring of the adamantane cage system is a nearly perfect chair. From the 1H and 13C nmr data, several stereoelectronic effects have been deduced. Copyright © 1990 Journal of Heterocyclic Chemistry

引用

页码：1355 / 1359

页数：5

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