REACTIONS OF EQ,EQ-RE2(CO)8(MECN)2 WITH PHENYLACETYLENE AND ALPHA-ETHYNYLESTRADIOL - A NEW SYNTHESIS OF ACETYLIDE COMPLEXES

被引：11

作者：

TOP, S

GUNN, M

JAOUEN, G

VAISSERMANN, J

DARAN, JC

THORNBACK, JR

机构：

[1] ECOLE NATL SUPER CHIM PARIS,CNRS,UA 403,11 RUE PIERRE & MARIE CURIE,F-75231 PARIS 052,FRANCE

[2] UNIV PARIS 06,CHIM MET TRANSIT LAB,F-75230 PARIS 05,FRANCE

[3] MEDGENIX SA,B-6220 FLEURUS,BELGIUM

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 414卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)83255-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex eq,,eq-Re2(CO)8(MeCN)2 reacts with phenylacetylene and alpha-ethynylestradiol to give the acetylide complexes (mu-H)(mu-C = CR)Re2(CO)7(MeCN) [1, R = Ph; 2, R = alpha-ethynylestradiol] and not the expected compounds (mu-H)(mu-C = CR)Re2(CO)8. The products were identified from their spectroscopic properties and by an X-ray structural determination in the case of 1. The alpha-ethynylestradiol complex exists in two diastereomeric forms.

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页码：C22 / C27

页数：6

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