The pulse radiolysis of carbon monoxide

被引：15

作者：

Willis, C.

Devillers, C.

机构：

[1] Ctr Etud Nucl Saclay, Serv Chim Phys, Gif Sur Yvette, France

[2] Atom Energy Canada Ltd, Chalk River Nucl Labs, Res Chem Branch, Chalk River, ON, Canada

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 01期

关键词：

D O I：

10.1016/0009-2614(68)80146-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Carbon monoxide has been irradiated with intense pulses of 1 MeV electrons and two transient absorption spectra have been observed. One of these consisted of a series of bands extending from 5000 - 8500 angstrom and the second a single line at 2479 angstrom. The species giving rise to the band system is probably C2O((3)Sigma) and that to the single line C(S-1). It is proposed that carbon atoms are not the exclusive precursors of C2O((3)Sigma) in the system and a reaction involving electronically excited carbon monoxide is occurring. CO* + CO -> C2O((3)Sigma) + O.

引用

页码：51 / 53

页数：3

共 11 条

[1]

DEVILLERS C, 1966, CR ACAD SCI C CHIM, V262, P1485

[2]

GROTH W, 1966, Z PHYS CHEM FRANKFUR, V32, P192

[3] MATRIX-ISOLATION INFRARED SPECTRUM OF FREE RADICAL CCO [J].