REACTIONS OF ME2NC(S)SN(SIME3)2 WITH METAL-HALIDES - CRYSTAL-STRUCTURE OF ME2NCS2ZRCL3.3PYRIDINE

被引：4

作者：

ROESKY, HW

MELLERREHBEIN, B

NOLTEMEYER, M

机构：

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 08期

关键词：

TELLURIUM; NIOBIUM; ZIRCONIUM; HAFNIUM; COMPLEXES; X-RAY;

D O I：

10.1515/znb-1991-0824

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Me2NC(S)SN(SiMe3)2 (1) reacts with TeCl4 and NbCl5 to yield Me2NC(S)SNTeCl2 (4) and Me2NC(S)SNNbCl3 (5), while the dithiocarbamate complexes 6 and 7 are formed with ZrCl4 and HfCl4. The crystal structure of 6 is reported. The reaction of Me2NC(S)SN = TiCl2.3py 2 with LiN(SiMe3)2 gives the tricyclic compound 8.

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页码：1117 / 1121

页数：5

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